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Beilstein J. Org. Chem. 2015, 11, 1796–1808, doi:10.3762/bjoc.11.195
Graphical Abstract
Figure 1: Dependences of the (blue) PCOE and (green) PNB mean hydrodynamic radius in CHCl3 on the (a) light ...
Figure 2: Hydrodynamic radius distributions (normalized by their maximum values) in the CHCl3 solutions of (b...
Figure 3: Stability of the primary carbene [Ru]=CHPh in the pure solvent (CDCl3).
Scheme 1: Formation of polyoctenamer-bound carbene by the interaction of Gr-1 with PCOE.
Figure 4: (a) Dependences of the normalized (red) [Ru]=CHPh and (blue) [Ru]=PCOE carbene concentrations on ti...
Scheme 2: Formation of polynorbornene-bound carbene by the interaction of Gr-1 with PNB.
Figure 5: (a) Dependences of the normalized (red) [Ru]=CHPh and (green) [Ru]=PNB carbene concentrations on ti...
Scheme 3: Elementary cross-metathesis reactions in the mixture of PCOE with PNB.
Figure 6: Dependences of the normalized (red) primary, (blue) PCOE, and (green) PNB carbene concentrations an...
Figure 7: The kinetics of NB-COE dyads formation under mixing conditions for the systems with (red) cin/cp = ...
Figure 8: The 1H NMR spectrum recorded after 10 min of the reaction between PCOE and Gr-1 at the initial conc...
Figure 9: The 1H NMR spectrum recorded after 653 min of the reaction between PNB and Gr-1 at the initial conc...
Figure 10: The 1H NMR spectrum recorded after 24 h of the reaction between PCOE, PNB, and Gr-1 at the initial ...
Figure 11: The 13C NMR spectrum recorded after 8 h of the reaction between PCOE, PNB, and Gr-1 at the initial ...